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Chemoselective and re-usable heterogeneous catalysts for the direct synthesis of hydrogen peroxide in the liquid phase under non-explosive conditions and in the absence of chemoselectivity enhancers

Paper ID Volume ID Publish Year Pages File Format Full-Text
43137 45956 2009 8 PDF Available
Title
Chemoselective and re-usable heterogeneous catalysts for the direct synthesis of hydrogen peroxide in the liquid phase under non-explosive conditions and in the absence of chemoselectivity enhancers
Abstract

Catalyst Pd/K2621 (K2621 = strongly acidic macroreticular resin from Bayer) is an effective catalyst for the direct synthesis of hydrogen peroxide in methanol at temperatures near 0 °C, under batch reactor conditions. Reaction conditions are non-explosive in character and no addition of selectivity enhancers is required. Selectivity up to 70% at 50% conversion is achieved.

Graphical abstractCatalyst Pd/K2621 (K2621 = strongly acidic macroreticular resin from Bayer) is an effective catalyst for the direct synthesis of hydrogen peroxide in methanol at temperatures near 0 °C, under batch reactor conditions. Reaction conditions are non-explosive in character and no addition of selectivity enhancers is required. Selectivity up to 70% at 50% conversion is achieved.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Hydrogen peroxide; Direct synthesis; Palladium (0); Nanoclusters; Organic supports
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Chemoselective and re-usable heterogeneous catalysts for the direct synthesis of hydrogen peroxide in the liquid phase under non-explosive conditions and in the absence of chemoselectivity enhancers
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 358, Issue 2, 1 May 2009, Pages 224–231
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Price after discount Only $4.95
100% Money Back Guarantee
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