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Structuration of LaMnO3 perovskite catalysts on ceramic and metallic monoliths: Physico-chemical characterisation and catalytic activity in methane combustion

Paper ID Volume ID Publish Year Pages File Format Full-Text
43273 45961 2008 14 PDF Available
Title
Structuration of LaMnO3 perovskite catalysts on ceramic and metallic monoliths: Physico-chemical characterisation and catalytic activity in methane combustion
Abstract

LaMnO3 perovskite was prepared by the citrate method and deposited on ceramic and metallic monoliths according to a dip coating or an orbital stirring procedure. Both types of structured catalysts were characterised by specific surface area measurements (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The parameters influencing the amount of deposited catalyst, such as the nature of the monolith and the coating technique, were investigated. Comparisons between structured and powdered catalysts showed a higher catalytic activity of the former. A better behaviour of structured LaMnO3 on metallic monoliths was observed at a lower temperature, and higher catalytic activities were observed for structured LaMnO3 on ceramic monoliths at a higher temperature. The influence of a diffusion limitation of the reaction rate in structured catalysts was observed.

Graphical abstractLaMnO3 perovskites were deposited on ceramic and metallic monoliths according to a dip coating or an orbital stirring procedure and characterised by different physico-chemical techniques (BET, SEM, XPS and XRD). Comparisons between structured and powdered catalysts showed a higher catalytic activity of the former. Metallic monoliths display better catalytic performances at low temperatures and the ceramic ones are more active at higher temperatures. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Perovskite; Metallic monolith; Ceramic monolith; Methane combustion
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Structuration of LaMnO3 perovskite catalysts on ceramic and metallic monoliths: Physico-chemical characterisation and catalytic activity in methane combustion
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 339, Issue 1, 15 April 2008, Pages 1–14
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Price after discount Only $4.95
100% Money Back Guarantee
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