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Effective catalysts, prepared from several hydrotalcites aged with and without microwaves, for the clean obtention of 2-phenylethanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
43337 45965 2007 7 PDF Available
Title
Effective catalysts, prepared from several hydrotalcites aged with and without microwaves, for the clean obtention of 2-phenylethanol
Abstract

Several Ni/Mg/Al hydrotalcites have been aged by different methods (conventional refluxing, conventional autoclaving, microwaves refluxing and microwaves autoclaving). The resulting catalysts have been tested in the hydrogenation of styrene oxide to obtain 2-phenylethanol, widely used in the perfumery industry. The catalysts obtained from the hydrotalcites aged under microwaves showed higher metallic areas than those obtained from the hydrotalcites aged by conventional heating. All catalysts showed total conversion and very high selectivity to 2-phenylethanol (around 95%) after 1 h of reaction. The higher metallic area and the more homogeneous distribution of low amounts of basic sites of these catalysts based on hydrotalcites when compared with other basic catalysts, as Ni-MgO systems, can explain these best catalytic results. After reusing 10 times, all catalysts showed high resistance to deactivation since they maintain high conversion and high selectivity values to 2-phenylethanol. However, some differences in their catalytic behaviour were observed that have been explained from H2-TPD studies.

Graphical abstractCatalysts obtained from Ni/Mg/Al hydrotalcites aged by different methods gives to total conversion and almost total selectivity to 2-phenylethanol in the hydrogenation of styrene oxide after 1 h of reaction. This has been explained by the higher metallic area and the more homogeneous distribution of low amounts of basic sites of these catalysts. After reusing 10 times they maintain high catalytic activity.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Hydrotalcite; Microwaves; 2-Phenylethanol
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Effective catalysts, prepared from several hydrotalcites aged with and without microwaves, for the clean obtention of 2-phenylethanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 331, 2007, Pages 19–25
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us