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One-pot synthesis of ethylene trithiocarbonate from ethylene carbonate

Paper ID Volume ID Publish Year Pages File Format Full-Text
43517 45974 2008 5 PDF Available
Title
One-pot synthesis of ethylene trithiocarbonate from ethylene carbonate
Abstract

Ethylene trithiocarbonate (ETTC) was synthesized in good to excellent yields and selectivities from a one-pot catalytic reaction of ethylene carbonate (EC) and CS2 in the presence of a lithium halide by using EC as a source of ethylene oxide (EO). The selectivity of ETTC was strongly affected by the rate of EC decomposition into EO and CO2. Lithium chloride, the least active catalyst for the EC decomposition, showed the highest yield and selectivity.

Graphical abstractEthylene trithiocarbonate (ETTC) was selectively synthesized from ethylene carbonate and CS2 in the presence of LiX (X = Cl, Br, I). The selectivity of ETTC was strongly affected by the rate of EC decomposition into EO and CO2. Lithium chloride, the least active catalyst for the EC decomposition, showed the highest yield and selectivity.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Ethylene carbonate; Ethylene trithiocarbonate; Cyclic trithiocarbonate; Cyclic carbonate; Ethylene oxide; Ionic liquids
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One-pot synthesis of ethylene trithiocarbonate from ethylene carbonate
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 337, Issue 2, 25 March 2008, Pages 168–172
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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