fulltext.study @t Gmail

Dinuclear metallocene complexes as catalyst precursors for homogeneous ethylene polymerization

Paper ID Volume ID Publish Year Pages File Format Full-Text
43567 45977 2008 7 PDF Available
Title
Dinuclear metallocene complexes as catalyst precursors for homogeneous ethylene polymerization
Abstract

Four dinuclear alkylidene-bridged zirconocene complexes were synthesized applying hydrozirconation reaction of α,ω-dienes with the “Schwartz’ reagent” and tested for the polymerization of ethylene. The polyethylenes obtained with alkylidene-bridged dinuclear complexes showed higher molecular weights Mw and polydispersities revealing that more catalytically active species exist in the polymerization system.

Graphical abstractFour dinuclear alkylidene-bridged zirconocene complexes were synthesized applying hydrozirconation reaction of α,ω-dienes with the “Schwartz’ reagent” and tested for the polymerization of ethylene. The polyethylenes obtained with alkylidene-bridged dinuclear complexes showed higher molecular weights Mw and polydispersities revealing that more than one catalytically active species exist in the polymerization system. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Metallocene complexes; Homogeneous catalysts; Ethylene polymerization; Polyethylene
First Page Preview
Dinuclear metallocene complexes as catalyst precursors for homogeneous ethylene polymerization
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 348, Issue 1, 30 September 2008, Pages 79–85
Authors
, , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us