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Epoxidation of cyclooctene with hydroperoxy sultams catalyzed by molybdenum boride

Paper ID Volume ID Publish Year Pages File Format Full-Text
43620 45979 2007 7 PDF Available
Title
Epoxidation of cyclooctene with hydroperoxy sultams catalyzed by molybdenum boride
Abstract

The hydroperoxy sultams (HPS) have been investigated in catalytic epoxidation reaction of cyclooctene. We have found that HPS can function as the epoxidation agents in the presence of molybdenum boride MoB as a catalyst. The reaction was sensitive to steric as well as electronic factors. The high epoxides yields were observed in the case of hydroperoxy sultams with chlorine atoms and especially favorable was hydroperoxide structure with α-position of chlorine atom to bond of nitrogen with aromatic ring.

Graphical abstractThe hydroperoxy sultams have been investigated in epoxidation reaction of cyclooctene catalyzed by MoB. It was shown hydroperoxides can function as the epoxidation agents. The high epoxides yields were observed in the case of hydroperoxy sultams with chlorine atoms.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Catalyst; Epoxidation; Hydroperoxide; Hydroperoxy sultam; Molybdenum boride
First Page Preview
Epoxidation of cyclooctene with hydroperoxy sultams catalyzed by molybdenum boride
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 323, 30 April 2007, Pages 174–180
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis