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Synergistic catalysis effect in SO2 reduction by CO over Sn–Zr-based catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
43634 45980 2008 10 PDF Available
Title
Synergistic catalysis effect in SO2 reduction by CO over Sn–Zr-based catalysts
Abstract

In this study, the synergistic effect observed in the SO2 reduction by CO over SnO2–ZrO2 catalysts was investigated in detail. From the reactivity tests of the various catalysts, it was established that the applicable mechanism of this study was different from the conventional mechanisms such as the redox and COS intermediate mechanisms. It could be explained by postulating that the synergistic effect of the Sn–Zr-based catalyst was obtained in the SO2 reduction by CO as the following mechanistic pathway: In the first step involving the redox mechanism, SO2 was converted into elemental sulfur and other by-products such as COS because of the lattice oxygen mobility afforded by the redox properties of the SnO2 catalyst. In the second step involving the COS intermediate mechanism, COS produced in the first step was the more effective reducing agent than CO and reacted with SO2 over the ZrO2 catalyst, and then the productivity of elemental sulfur was improved. At that time, the reaction rate of SO2 + 2COS → 3S + 2CO2 must have been faster than that of CO + S → COS. The high reactivity of the SnO2–ZrO2 (Sn/Zr = 2/1) catalyst at low temperature was thus caused by a synergistic effect resulting of the simultaneous interaction between the redox mechanism and COS intermediate mechanism.

Graphical abstractThe synergistic effect, which was observed in SO2 reduction by CO over SnO2–ZrO2 catalysts, was investigated in detail. As a result, it is suggested that the high reactivity, SO2 conversion of about 100%, of SnO2–ZrO2 (Sn/Zr = 2/1) catalyst at 325 °C was caused by the synergistic effect resulting from the interaction between the redox mechanism and COS intermediate mechanism.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
SO2 reduction by CO; Sn–Zr-based catalyst; Redox mechanism; COS intermediate mechanism; Synergistic effect
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 337, Issue 1, 15 March 2008, Pages 29–38
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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