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One-pot catalytic synthesis of higher aliphatic ketones

Paper ID Volume ID Publish Year Pages File Format Full-Text
43723 45985 2007 5 PDF Available
Title
One-pot catalytic synthesis of higher aliphatic ketones
Abstract

The catalytic synthesis of high molecular weight aliphatic ketones by reductive condensation of lower molecular weight ketones was achieved by using CO in the presence of a multifunctional catalyst containing copper dispersed on alumina. The useful combination of condensation, water gas shift and hydrogenation reactions in a one-pot reaction allowed high yields of methylisobutylketone from acetone.

Graphical abstractThe catalytic synthesis of high molecular weight aliphatic ketones by reductive condensation of lower molecular weight ketones was achieved by using CO in the presence of a multifunctional catalyst containing copper dispersed on alumina. The useful combination of condensation, water gas shift and hydrogenation reactions in a one-pot reaction allowed high yields of methylisobutylketone from acetone.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Heterogeneous catalysis; Ketones; Copper; Alumina; Methylisobutylketone; Carbon monoxide
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 321, Issue 1, 29 March 2007, Pages 35–39
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
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