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Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
43743 45986 2007 7 PDF Available
Title
Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions
Abstract

We have synthesized and characterized a novel copper metalated polymeric matrix of modified nucleobase cytosine that catalyses oxidation of phenolic substrates. This metalated polymer is insoluble in common organic solvents, thus catalysis is heterogeneous in nature so that the material can be reused. The molecular structure of the monomer and the metalated monomer, a Michaelis–Menten kinetic analysis of oxidative transformations using different phenolic substrates and mechanistic investigations are presented in this paper.

Graphical abstractThis report describes a novel cytosine containing copper metalated polymeric matrix possessing phenol oxidative and coupling activities. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Cytosine; Copper; Heterogeneous catalysis; Phenol oxidation
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Kinetic characterization of a bioinspired, heterogeneously active macromolecular catalyst for phenol oxidation and coupling reactions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 316, Issue 1, 2 January 2007, Pages 100–106
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us