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Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
43788 45988 2006 6 PDF Available
Title
Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts
Abstract

The synthesis of dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in the presence of polymer-supported phase-transfer catalysts has been investigated. It was revealed that polymer-bound quaternary ammonium and polyethylene glycol catalysts were more active than their soluble forms. High yields (60–92%) of the products were obtained. The catalyst could be recycled several times with no appreciable loss of activity.

Keywords
Dialkyl peroxides; Hydroperoxides; Polymer-supported phase-transfer catalysts; Triphase catalysis
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Synthesis of dialkyl peroxides in the presence of polymer-supported phase-transfer catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 309, Issue 1, 17 July 2006, Pages 85–90
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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