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Water-soluble manganese(III) salen complex as a mild and selective catalyst for oxidation of alcohols

Paper ID Volume ID Publish Year Pages File Format Full-Text
43842 45991 2006 6 PDF Available
Title
Water-soluble manganese(III) salen complex as a mild and selective catalyst for oxidation of alcohols
Abstract

Dicationic Mn(III) salen, containing phosphonium groups at 5,5′-positions of salen ligand, was used as an efficient and selective catalyst for oxidation of alcohols to their corresponding aldehyde or ketone derivatives at room temperature in good to excellent yields. The effect of different solvents was studied in the oxidation of 4-methoxybenzyl alcohol, CH3CN/H2O was better solvent. Also the effect of the oxygen donors such as NaIO4, Bu4NIO4, Oxone, H2O2, H2O2/urea, NaOCl and tert-BuOOH was studied in the oxidation of 4-methoxybenzyl alcohol and selected NaIO4 as oxygen donor.

Graphical abstractMild and efficient oxidation of alcohols with sodium periodate catalysed by water-soluble Mn(salen)OAc is reported. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Alcohols; Aldehydes; Ketones; Oxidation; Manganese salen; Periodate
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Water-soluble manganese(III) salen complex as a mild and selective catalyst for oxidation of alcohols
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 315, 23 November 2006, Pages 52–57
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Full-text PDF Download
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