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Catalytic condensation process for the preparation of organic peroxides from tert-butyl hydroperoxide and benzylic alcohols

Paper ID Volume ID Publish Year Pages File Format Full-Text
43854 45991 2006 3 PDF Available
Title
Catalytic condensation process for the preparation of organic peroxides from tert-butyl hydroperoxide and benzylic alcohols
Abstract

The Wells–Dawson tungsten heteropolyacid H6P2W18O62 catalyzes the formation of dissymmetric peroxides from tert-butyl hydroperoxide and various benzylic alcohols. In some cases, these catalytic conditions led to benzylic ethers as side compounds.

Graphical abstractThe selectivity depends on the nature of R1 and R2 substituents. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Heteropolyacid; Catalysis; tert-Butyl hydroperoxide; Benzylic alcohols; Peroxides
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Catalytic condensation process for the preparation of organic peroxides from tert-butyl hydroperoxide and benzylic alcohols
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 315, 23 November 2006, Pages 150–152
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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