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Ni-nanoparticles: A mild chemo-selective catalyst for synthesis of thioethers

Paper ID Volume ID Publish Year Pages File Format Full-Text
44125 46004 2007 6 PDF Available
Title
Ni-nanoparticles: A mild chemo-selective catalyst for synthesis of thioethers
Abstract

A novel method for selective oxidative coupling of a thiol with an alcohol to form the corresponding thioether in the presence of other functional groups, viz. –NH2, –X, –NO2, –OCH3, etc., under air atmosphere using Ni-nanoparticles is described. Ni-nanoparticles act as a novel selective catalyst, which efficiently reduces the reaction time and increases the yield without producing any side products. Ni-nanoparticles have high TON and TOF so they can be easily recycled.

Graphical abstractA novel method for selective oxidative coupling of a thiol with an alcohol to form the corresponding thioether in the presence of other functional groups, viz. –NH2, –X, –NO2, –OCH3, etc., under air atmosphere using Ni-nanoparticles is described. Ni-nanoparticles act as a novel selective catalyst, which efficiently reduces the reaction time and increases the yield without producing any side products. Ni-nanoparticles have high TON and TOF so they can be easily recycled. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Oxidative coupling; Thiols; Thioether; TON and TOF
First Page Preview
Ni-nanoparticles: A mild chemo-selective catalyst for synthesis of thioethers
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 317, Issue 2, 7 February 2007, Pages 210–215
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis