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Epoxidation of alkenes by a readily prepared and highly active and reusable heterogeneous molybdenum-based catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
44188 46007 2006 6 PDF Available
Title
Epoxidation of alkenes by a readily prepared and highly active and reusable heterogeneous molybdenum-based catalyst
Abstract

Polymer-bound piperazine was readily prepared from Merrifield resin and was used as a robust support for immobilization of molybdenum hexacarbonyl. This polymer-supported molybdenum catalyst shows high activity in the epoxidation of various alkenes in the presence of tert-butylhydroperoxide (TBHP). This new heterogenized molybdenum catalyst can be recovered and reused for eight times without loss of its activity.

Graphical abstractThe catalytic activity of Mo(CO)6 supported on polystyrene in the epoxidation of alkenes with TBHP was studied in CCl4. Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Molybdenum carbonyl; Heterogeneous catalyst; Epoxidation; tert-Butylhydroperoxide
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Epoxidation of alkenes by a readily prepared and highly active and reusable heterogeneous molybdenum-based catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 299, 17 January 2006, Pages 131–136
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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