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Preparation of a hybrid organic–inorganic material containing macrocyclic triolefinic 15-membered palladium(0) complex: Catalytic activity in Suzuki cross-coupling and butadiene telomerization reactions

Paper ID Volume ID Publish Year Pages File Format Full-Text
44276 46013 2006 8 PDF Available
Title
Preparation of a hybrid organic–inorganic material containing macrocyclic triolefinic 15-membered palladium(0) complex: Catalytic activity in Suzuki cross-coupling and butadiene telomerization reactions
Abstract

The synthesis of a bis-silylated 15-membered azatriolefinic macrocycle is described as well as its co-gelification with tetraethyl orthosilicate. The resulting material was treated with Pd(dba)2 affording an hybrid organic–inorganic material containing macrocyclic palladium(0) complex covalently bonded to the silica matrix. The activity of this material as catalyst or precatalyst in Suzuki cross-coupling and telomerization of butadiene with methanol and phenol is presented.

Keywords
Cross-coupling; Macrocycles; Palladium supported catalyst; Sol–gel processes; Telomerization
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Preparation of a hybrid organic–inorganic material containing macrocyclic triolefinic 15-membered palladium(0) complex: Catalytic activity in Suzuki cross-coupling and butadiene telomerization reactions
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 297, Issue 2, 6 January 2006, Pages 117–124
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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