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Electrocatalytic reductive dehalogenation of polyhalogenated phenols in aqueous solution on Ag electrodes

Paper ID Volume ID Publish Year Pages File Format Full-Text
44381 46020 2007 4 PDF Available
Title
Electrocatalytic reductive dehalogenation of polyhalogenated phenols in aqueous solution on Ag electrodes
Abstract

The electrocatalytic properties of Ag towards the dehalogenation of a variety of polychloro- and polybromo-phenols in basic aqueous solution have been evaluated. Experimental evidence is presented that Ag exhibited powerful electrocatalytic activity for dehalogenation of polyhalogenated phenols to less, or non-halogenated phenols.

Graphical abstractAg appears to be an excellent electrocatalytic material for direct electrodehalogenation of phenolic halides in basic aqueous solution. Complete debromination of polybrominated phenols with excellent current efficiency can be successfully achieved without resorting to the use of organic solvents. The more resistant polychlorinated phenols can also be dehalogenated partially in the catalytic system.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Reductive dehalogenation; Polyhalogenated phenol; Ag electrode; Aqueous solution
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Electrocatalytic reductive dehalogenation of polyhalogenated phenols in aqueous solution on Ag electrodes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 324, 17 May 2007, Pages 83–86
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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