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Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes

Paper ID Volume ID Publish Year Pages File Format Full-Text
44408 46024 2006 5 PDF Available
Title
Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes
Abstract

Aldehydes undergo smooth nucleophilic addition with allyl-n-tributylstannane in the presence of sulphamic acid (5 mol%, SA) under extremely mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high chemoselectivity. The catalyst can be recovered by simple filtration and can be recycled in subsequent reactions. The method is simple, cost-effective and environmentally benign.

Keywords
Sulphamic acid (SA); Allyl-n-tributylstannane; Homoallylic alcohols; Chemoselectivity
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Sulphamic acid: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 306, 7 June 2006, Pages 192–196
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us