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Kinetic considerations of H2 assisted hydrocarbon selective catalytic reduction of NO over Ag/Al2O3: II. Kinetic modelling

Paper ID Volume ID Publish Year Pages File Format Full-Text
44491 46034 2006 7 PDF Available
Title
Kinetic considerations of H2 assisted hydrocarbon selective catalytic reduction of NO over Ag/Al2O3: II. Kinetic modelling
Abstract

A kinetic study of the reduction of NO by n-octane performed isothermally (200 °C) at steady state conditions over an active Ag/alumina catalyst was carried out in the presence of hydrogen. The mathematical model was based on a supposed reaction mechanism, which among other steps includes molecular adsorption of NO and CO as well as dissociative adsorption of H2 and O2. Formation of CO2 is assumed to go through oxidation of CO. A comparison between experimental data and simulations revealed that the developed mathematical model is able to describe the observed reduction of NO in presence of H2 sufficiently well.

Keywords
HC-SCR; Hydrogen effect; Silver; Kinetic modelling
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Kinetic considerations of H2 assisted hydrocarbon selective catalytic reduction of NO over Ag/Al2O3: II. Kinetic modelling
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 304, 10 May 2006, Pages 86–92
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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