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Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis

Paper ID Volume ID Publish Year Pages File Format Full-Text
44549 46041 2006 8 PDF Available
Title
Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis
Abstract

A new versatile heterogeneous catalyst for olefin metathesis based on rhenium (VII) oxide supported on organized mesoporous alumina was developed. This catalyst is suitable for metathesis of linear olefins, α-, ω-dienes as well as ring-opening metathesis polymerization of cycloalkenes and cross-metathesis of cycloolefins with linear olefins. This catalyst was found to operate under mild reaction conditions and its activity was much higher than that of corresponding catalyst based on conventional alumina. Catalyst can be used repeatedly and can be easily reactivated. Influence of the catalyst pore size on activity as well as selectivity in individual methathesis reactions was established.

Keywords
Organized mesoporous alumina; Rhenium oxide; Alkene metathesis; Ring-opening metathesis polymerization
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Rhenium oxide supported on organized mesoporous alumina — A highly active and versatile catalyst for alkene, diene, and cycloalkene metathesis
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 302, Issue 2, 11 April 2006, Pages 193–200
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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