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Isomerization of linear alkenes on Amberlyst 15

Paper ID Volume ID Publish Year Pages File Format Full-Text
44630 46046 2006 9 PDF Available
Title
Isomerization of linear alkenes on Amberlyst 15
Abstract

The kinetics of the isomerization of 1-butene to cis-2-butene and trans-2-butene, of 1-pentene to cis-2-pentene and trans-2-pentene as well as of 1-hexene to cis-2-hexene and trans-2-hexene on sulfonated copolymer Amberlyst 15 in the gas phase was investigated. The Langmuir–Hinshelwood equations were adjusted to the results of the kinetic experiment using the values of adsorption equilibrium constants of the reactants from the adsorption measurements separately taken. The calculations were done by the Levenberg–Marquardt least-squares method using the Origin Microcal program.

Keywords
Isomerization; 1-Butene; Cis-2-butene; Trans-2-butene; 1-Pentene; Cis-2-pentene; Trans-2-pentene; 1-Hexene; Cis-2-hexane; Trans-2-hexane; Langmuir–Hinshelwood kinetics; Amberlyst 15
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Isomerization of linear alkenes on Amberlyst 15
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 301, Issue 2, 24 February 2006, Pages 232–240
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis