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Selective thermomorphic biphasic hydroformylation of higher olefins catalyzed by HRhCO(PPh3)3/P(OPh)3

Paper ID Volume ID Publish Year Pages File Format Full-Text
44692 46056 2006 8 PDF Available
Title
Selective thermomorphic biphasic hydroformylation of higher olefins catalyzed by HRhCO(PPh3)3/P(OPh)3
Abstract

A thermomorphic approach to rhodium-catalyzed biphasic hydroformylation of higher olefins (C > 6) has been developed based on HRhCO(PPh3)3/P(OPh)3/propylene carbonate/n-heptane catalytic system. The catalyst system showed excellent selectivity toward the desired linear aldehyde (n/i ratio > 8) and high catalytic activity demonstrated by the efficient recycling without significant loss of the catalyst activity. The effects of the temperature, the total pressure, the ratio of CO/H2, the reaction time and the type of ligand have been thoroughly studied.

Keywords
Hydroformylation; Thermomorphic; Biphasic; Aldehydes; Rhodium; 1-Octene; Phosphine; Phosphite; Syngas
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Selective thermomorphic biphasic hydroformylation of higher olefins catalyzed by HRhCO(PPh3)3/P(OPh)3
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis A: General - Volume 303, Issue 2, 28 April 2006, Pages 158–165
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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