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A novel W-doped Ni-Mg mixed oxide catalyst for CO2 methanation

Paper ID Volume ID Publish Year Pages File Format Full-Text
44976 46390 2016 9 PDF Available
Title
A novel W-doped Ni-Mg mixed oxide catalyst for CO2 methanation
Abstract

•NiWMgOx catalysts showed excellent CO2 methanation activity.•Adding W improved the catalyst stability and anti-CO-poisoning ability.•Tungsten also facilitated the formation of more active monodentate formate.

Novel Ni-W-Mg mixed oxide catalysts (NiWMgOx) were prepared by homogeneous precipitation and attempted for the methanation of CO2. Adding W remarkably promoted the activity with improved stability, anti-CO-poisoning ability and resistance against coke formation compared to the undoped NiMgOx catalyst. The superior reactivity of monodentate formate towards hydrogenation than that of bidentate formate species was identified by DRIFTS analysis and the formation of more active monodentate formate species was indisputably facilitated by W additives, leading to the greatly enhanced catalytic activity. H2-TPR and CO2-TPD characterization showed that doping W increased the number of stable CO2 adsorption sites and helped in anchoring the Ni sites as a result of strengthened Ni-Mg interaction, both of which were responsible for the enhanced CO2 methanation activity and the improved resistance against sintering.

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Keywords
CO2 methanation; Ni-W-Mg mixed oxide; Ni-Mg interactions; Monodentate formate
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A novel W-doped Ni-Mg mixed oxide catalyst for CO2 methanation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 196, 5 November 2016, Pages 108–116
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us