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Preparation of Ru/graphene-meso-macroporous SiO2 composite and their application to the preferential oxidation of CO in H2-rich gases

Paper ID Volume ID Publish Year Pages File Format Full-Text
45042 46395 2014 11 PDF Available
Title
Preparation of Ru/graphene-meso-macroporous SiO2 composite and their application to the preferential oxidation of CO in H2-rich gases
Abstract

•Graphene can be perfectly uniform cover on the wall of the macropores SiO2.•GE-SiO2 monolith possesses the advantages providing by hierarchically porous.•Ru/GE-SiO2 catalysts show superior low-temperature activity for CO-PROX.

Preparation for graphene (GE)-meso-macroporous SiO2 composite was studied, the composite was used as the support for Ru and the resulted catalyst was applied to the preferential oxidation of CO (CO-PROX) in H2-rich gases. The composite was characterized by using techniques of SEM, TEM, XRD, TPR, N2 adsorption/desorption and XPS. In the preparation, polystyrene foam and a tri-block copolymer of P123 were used as the template for the macropores and the mesopores, respectively. In addition to the macro and the meso pores, there are narrow slit-like pores with width of several nanometers between GE and SiO2. The highly dispersed Ru nanoparticle can be loaded on the surface of GE in the composite by impregnating. Thus prepared Ru/GE-SiO2 showed very good catalytic performance for CO-PROX, especially exhibited high activity at low temperature. The GE-SiO2 composite should possess the properties of both meso-macroporous oxides and graphene, and is a kind of new promising material, in which SiO2 can be replaced by other oxides.

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Keywords
Graphene; Meso-macroporous; Preferential oxidation; Ruthenium; Silica
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Preparation of Ru/graphene-meso-macroporous SiO2 composite and their application to the preferential oxidation of CO in H2-rich gases
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volumes 154–155, July–August 2014, Pages 82–92
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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Any Questions? feel free to contact us