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Structure sensitivity of selective catalytic reduction of NO with propylene over Cu-doped Ti0.5Zr0.5O2−δ catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
45583 46416 2015 10 PDF Available
Title
Structure sensitivity of selective catalytic reduction of NO with propylene over Cu-doped Ti0.5Zr0.5O2−δ catalysts
Abstract

•Hierarchical structure Cu-doped Ti0.5Zr0.5O2-δ was fabricated by hydrothermal method.•Well-organized morphology promoted the generation of active sites.•N-containing organic intermediates only formed on the Hy-Sample.

The structure sensitivity of selective catalytic reduction (SCR) of NO with propylene over Cu-doped Ti0.5Zr0.5O2−δ catalysts was investigated systematically in a series of characterizations and in situ DRIFT spectroscopy. A Cu-doped Ti0.5Zr0.5O2−δ catalyst with a hierarchical structure was fabricated successfully using a hydrothermal method (Hy-Sample), and shown to exhibit excellent SCR performance with high reaction rate and turnover frequency (TOF). The physico-chemical properties, mass transfer, and SCR activity of the catalyst depended on the preparation method. Another sample of Cu-doped Ti0.5Zr0.5O2−δ catalyst prepared using a co-precipitation method (Co-Sample) exhibited a disordered, irregular morphology, whose SCR activity, as determined in a fixed bed reactor, was significantly lower than that of Hy-Sample. In comparison, Hy-Sample possessed an enhanced redox property, and its highly ordered morphology greatly promoted the generation of active sites, including the fine-dispersed CuO species and surface adsorbed oxygen. Consequently, NO and C3H6 were readily adsorbed and activated over Hy-Sample and induced the formation of important intermediates with high reactivity, such as isocyanate (−NCO) and cyanide (−CN) species. However, the activation capacity of Co-Sample toward reactants was very weak, and the sequential deficiency of N-containing organics could be the primary reason for the poor SCR activity of Co-Sample.

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Keywords
Cu-doped Ti0.5Zr0.5O2−δ; Hierarchical morphology; In situ DRIFTS; Selective catalytic reduction; Structure sensitive
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Structure sensitivity of selective catalytic reduction of NO with propylene over Cu-doped Ti0.5Zr0.5O2−δ catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 165, April 2015, Pages 519–528
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us