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Cellulose hydrothermal conversion promoted by heterogeneous Brønsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid

Paper ID Volume ID Publish Year Pages File Format Full-Text
46805 46449 2011 11 PDF Available
Title
Cellulose hydrothermal conversion promoted by heterogeneous Brønsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid
Abstract

Crystalline cellulose treated in hydrothermal conditions (190 °C, 24 h) is partially solubilised, 30%, into water soluble oligosaccharides/polymers with the formation of small amounts of glucose and 5-HMF. In the presence of solid Brønsted catalysts such as Cs2HPW12O40 and HY zeolite, the extent of the cellulose depolymerisation was not changed when no leaching occurred. However, a quite different products distribution was obtained, in favour of further transformations of glucose and HMF in levulinic and formic acids. On the opposite, solid Lewis acids such as tungstated zirconia (ZrW) and tungstated alumina (AlW) exhibited a remarkable promoting effect on the cellulose depolymerisation which was raised up to 45% while an unexpected decrease of the proportion of water soluble oligosaccharides/polymers was observed. Yields of 27 mol% and 18.5 mol% in lactic acid were achieved on AlW and ZrW, respectively. Moreover, these tungsten based Lewis acids exhibited a good stability and recyclability. The efficiency of the solid Lewis acids ZrW and AlW to produce lactic acid directly from crystalline cellulose was explained by a positive synergy between water autoprotolysis responsible of the cellulose depolymerisation into soluble intermediates which are further converted on the solid Lewis catalyst surface.

Graphical abstract.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Solid Lewis acids catalysts exhibited a promoting effect on the cellulose depolymerisation. ► High yields in lactic acid are obtained with the solid Lewis acids catalysts. ► Solid Brønsted catalysts are unstable for cellulose conversion in hydrothermal conditions.

Keywords
Cellulose hydrolysis; Solid Lewis acid catalysts; Tungstated zirconia; Tungstated alumina; Lactic acid
First Page Preview
Cellulose hydrothermal conversion promoted by heterogeneous Brønsted and Lewis acids: Remarkable efficiency of solid Lewis acids to produce lactic acid
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 105, Issues 1–2, 9 June 2011, Pages 171–181
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis