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Effect of preparation atmosphere of Pt–SnOx/C catalysts on the catalytic activity for H2/CO electro-oxidation

Paper ID Volume ID Publish Year Pages File Format Full-Text
47336 46468 2010 8 PDF Available
Title
Effect of preparation atmosphere of Pt–SnOx/C catalysts on the catalytic activity for H2/CO electro-oxidation
Abstract

Pt–SnOx/C catalysts were prepared in a polyol process under Ar, sequential Ar and air, and air atmospheres in combination with a high temperature reduction treatment. The composition, structure, morphology and oxidation state of the prepared catalysts were characterized by Inductively Coupled Plasma-Atom Emission Spectroscopy, X-ray diffraction, scanning transmission electron microscopy and X-ray photoelectron spectroscopy. The electrochemical activities were evaluated by CO stripping voltammetry and single cell test in combination with in situ IR reflection absorption spectroscopy (IRRAS). The polyol-synthesized Pt–SnOx/C catalysts prepared under different atmospheres had a similar bulk composition, particle size and lattice parameter, however, the Pt–SnOx/C catalyst prepared under Ar atmosphere possessed a greater proportion of Sn(II) species than the other Pt–SnOx/C catalysts. Electrochemical and in situ IRRAS measurements indicated that the Pt–SnOx/C catalyst under Ar atmosphere had the greatest CO tolerance in proton electrolyte fuel cell among the Pt–SnOx/C catalysts.

Keywords
Pt–SnOx/C catalyst; Preparation atmosphere; CO tolerance
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Effect of preparation atmosphere of Pt–SnOx/C catalysts on the catalytic activity for H2/CO electro-oxidation
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 98, Issues 1–2, 20 July 2010, Pages 86–93
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
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