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Microwave-activated direct synthesis of acrylonitrile from glycerol under mild conditions: Effect of niobium as dopant of the V-Sb oxide catalytic system

Paper ID Volume ID Publish Year Pages File Format Full-Text
47473 46473 2010 5 PDF Available
Title
Microwave-activated direct synthesis of acrylonitrile from glycerol under mild conditions: Effect of niobium as dopant of the V-Sb oxide catalytic system
Abstract

Glycerol is a major by-product in biodiesel production, which raises a critical need to develop efficient valorization processes. This study shows how both conventional thermal activation and microwave irradiation are able to selectively transform glycerol into acrylonitrile, this performance is modulated by niobium doping of SbnV/Al2O3 catalysts under mild reaction conditions. To the best of our knowledge, we report the highest selectivity (83.8%) to acrylonitrile from glycerol at good conversion values (46.8%).

Keywords
Glycerol; Acrylonitrile; Biomass; Microwave activation; Catalytic process; Sustainability
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Microwave-activated direct synthesis of acrylonitrile from glycerol under mild conditions: Effect of niobium as dopant of the V-Sb oxide catalytic system
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 95, Issues 3–4, 6 April 2010, Pages 192–196
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us