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Silver supported mesoporous SBA-15 as potential catalysts for SCR NOx by ethanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
47598 46477 2009 9 PDF Available
Title
Silver supported mesoporous SBA-15 as potential catalysts for SCR NOx by ethanol
Abstract

Reduction of nitrogen oxides (NOx) in a lean exhaust gases has become one of the most important environmental concerns. This study compared the performances of DeNOx and the properties of silver/mesoporous aluminosilica synthesized by different methods. Silver nanoparticles were obtained after calcination of the materials prepared by incipient wetness or by the excess solvent impregnation of Al-SBA-15 support by silver nitrate. On the other hand, the silver nitrate was introduced on the synthesis gel of SBA-15. The solid product was used as support to deposit aluminium. The effect of synthesis method on silver incorporation and the porous structure of the resulting solids has been examined. Some techniques had been applied, such as: elemental analysis, X-ray diffraction (XRD), N2 sorption measurements and Transmission Electron Microscopy (TEM). The nature of silver species in these catalysts was investigated by XPS measurements, high angle XRD, high resolution TEM and TPR/H2 (temperature-programmed reduction). The resulting materials were tested in the selective catalytic reduction of NOx by ethanol in the presence of oxygen. Finally, the effect of H2 on the DeNOx activity was also investigated.The impregnation method of Al-SBA-15 by silver nitrate influences the size, the location of the particles and the catalytic activity. To maintain a higher DeNOx activity, the percentage of aluminium loading and the feed of H2 gases should be increased.

Keywords
Silver; Mesoporous silica or aluminosilica; NOx; Ethanol
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Silver supported mesoporous SBA-15 as potential catalysts for SCR NOx by ethanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 91, Issues 3–4, 28 September 2009, Pages 640–648
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us