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Formation of active sites on Ir/WO3–SiO2 for selective catalytic reduction of NO by CO

Paper ID Volume ID Publish Year Pages File Format Full-Text
48174 46496 2008 6 PDF Available
Title
Formation of active sites on Ir/WO3–SiO2 for selective catalytic reduction of NO by CO
Abstract

Pretreatment conditions for the activation of Ir/WO3–SiO2 for the selective catalytic reduction of NO by CO in the presence of excess O2 were studied. Sequential treatment involving calcination in the presence of O2 and H2O followed by reduction and then re-oxidation under mild conditions was found to effectively activate Ir/WO3–SiO2. Temperature-programmed desorption during calcination, X-ray diffraction, and temperature-programmed reduction by H2 revealed that calcination was necessary for oxidative removal of the NH3 ligands from the iridium precursor, that reduction produced metallic iridium and partially reduced tungsten oxide, and that re-oxidation produced tungsten oxide with low reducibility. Transmission electron microscopy revealed that Ir was supported on finely dispersed tungsten oxide and that the iridium particle size after the sequential activation was 1–1.5 nm.

Keywords
Nitrogen oxide; Carbon monoxide; Iridium; Selective catalytic reduction; Tungsten oxide; Silica
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Formation of active sites on Ir/WO3–SiO2 for selective catalytic reduction of NO by CO
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 84, Issues 3–4, 1 December 2008, Pages 420–425
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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