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Evidence for the formation, isomerization and decomposition of organo-nitrite and -nitro species during the NOx reduction by C3H6 on Ag/Al2O3

Paper ID Volume ID Publish Year Pages File Format Full-Text
48558 46512 2007 5 PDF Available
Title
Evidence for the formation, isomerization and decomposition of organo-nitrite and -nitro species during the NOx reduction by C3H6 on Ag/Al2O3
Abstract

The formation of organo-nitrite and -nitro species (R-ONO and R-NO2) as intermediates during the selective catalytic reduction (SCR) of NOx by C3H6 over Ag/Al2O3 was investigated by temperature-programmed desorption (TPD) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The addition of KBr to Ag/Al2O3 catalyses the isomerization of R-NO2 to R-ONO on KBr-Ag/Al2O3, which confirms the presence of R-NO2 on Ag/Al2O3.

Keywords
R-NO2; R-ONO; TPD; DRIFTS; KBr dilution
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Evidence for the formation, isomerization and decomposition of organo-nitrite and -nitro species during the NOx reduction by C3H6 on Ag/Al2O3
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 75, Issues 3–4, 26 September 2007, Pages 298–302
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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