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Deactivation and reactivation of Pd/C catalyst used in repeated batch hydrodechlorination of PCE

Paper ID Volume ID Publish Year Pages File Format Full-Text
49047 46543 2007 6 PDF Available
Title
Deactivation and reactivation of Pd/C catalyst used in repeated batch hydrodechlorination of PCE
Abstract

The deactivation of the palladium catalyst supported on activated carbon (Pd/C) was investigated in the repeated runs of the catalytic hydrodechlorination (HDC) of tetrachloroethylene (PCE) in pure MeOH and in 50/50 water–MeOH mixture with catalyst and solvent reuse at 20 °C and atmospheric pressure. Faster PCE dechlorination rates and slightly slower catalyst deactivation were observed in the runs in the mixture than in those in pure MeOH. Washing by stirring in either water or MeOH could completely recover the initial activity of the catalyst repeatedly used in the mixture, but could only partially recover that of the catalyst repeatedly used in pure MeOH. These results clearly show the superiority of using a 50/50 water–MeOH mixture over pure MeOH as a solvent for the HDC of PCE.

Keywords
Pd/C; Catalyst reuse; 50/50 water–MeOH mixture; Catalytic activity; Deactivation; Reactivation
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Deactivation and reactivation of Pd/C catalyst used in repeated batch hydrodechlorination of PCE
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Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 71, Issues 1–2, 8 February 2007, Pages 64–69
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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