fulltext.study @t Gmail

Mechanistic study of cyclohexene oxidation and its use in modification of industrial waste organics

Paper ID Volume ID Publish Year Pages File Format Full-Text
49083 46547 2006 9 PDF Available
Title
Mechanistic study of cyclohexene oxidation and its use in modification of industrial waste organics
Abstract

Mechanistic study of oxidation of cyclohexene was carried out over a copper complex and its immobilized analogue supported on organically modified silica. The immobilized complex has been characterized by using atomic absorption spectrophotometry (AAS), FT-IR, EPR and UV–vis spectroscopic studies and SEM image analysis. Catalytic oxidation of cyclohexene was carried out over this copper complex and the immobilized analogue with different oxidants like dilute aqueous hydrogen peroxide and tert-butyl hydroperoxide at ambient conditions. Acetonitrile and water was used as solvent and dispersion medium, respectively, with or without additional acid in different sets of oxidation reactions. The mechanism of hydride shift initiated the study of benzene oxidation, which gave quinone as major product. The activity of the immobilized catalyst remains nearly the same after four cycles, suggesting the true heterogeneous nature of the catalyst.

Keywords
Allylic oxidation; Copper-complex; Benzene; Oxidation; Immobilization; Peroxides; 2-Cyclohexene-1-one
First Page Preview
Mechanistic study of cyclohexene oxidation and its use in modification of industrial waste organics
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Applied Catalysis B: Environmental - Volume 68, Issues 1–2, 26 October 2006, Pages 12–20
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us