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Enantioselective Diels–Alder reactions using a G-triplex DNA-based catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
49248 46730 2016 3 PDF Available
Title
Enantioselective Diels–Alder reactions using a G-triplex DNA-based catalyst
Abstract

•We first used G-triplex–Cu2 + as an enantioselective catalyst.•Diels–Alder reaction could be catalyzed by our complex.•We measured the reaction kinetics.•The substrate specifity was well studied.

In this study, it was found that the G-triplex DNA could be used as an enantioselective catalyst without further addition of ligands in Diels–Alder reactions when coordinated with copper ions, for the first time. The efficiency and selectivity of the catalyst were investigated. The kinetic measurements were made using ultraviolet (UV) light. The stability of the catalyst in aqueous buffer was confirmed by circular dichroism (CD) and nuclear magnetic resonance (NMR) spectra.

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Keywords
Diels–Alder; G-triplex; DNA; Asymmetric catalysis; Enantioselectivity
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Enantioselective Diels–Alder reactions using a G-triplex DNA-based catalyst
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 74, 10 January 2016, Pages 16–18
Authors
, , , , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us