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Calcium catalyzed Mukaiyama–Mannich addition of silyl enol ethers to nitrones

Paper ID Volume ID Publish Year Pages File Format Full-Text
49279 46731 2016 4 PDF Available
Title
Calcium catalyzed Mukaiyama–Mannich addition of silyl enol ethers to nitrones
Abstract

•Calcium catalyzed addition of ketone-derived silyl enol ethers to N-phenyl nitrones•Use of commercially available calcium(II) complex.•Calcium(II) is a relatively cheap, abundant, benign metal.•Synthesis of β-(silyloxy)amino carbonyl compounds

A method for synthesizing β-(silyloxy)amino carbonyls through the addition of ketone-derived silyl enol ethers to N-phenyl nitrones has been developed. The transformation is catalyzed by a commercially available calcium(II) complex affording β-(silyloxy)amino carbonyls in good to excellent yield.

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Keywords
Calcium catalysis; Nitrones; Silyl enol ethers; β-amino carbonyls; Green catalysis; Mukaiyama–Mannich
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Calcium catalyzed Mukaiyama–Mannich addition of silyl enol ethers to nitrones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 79, 5 April 2016, Pages 35–38
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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