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Bi (NO3)3·5H2O and cellulose mediated Cu-NPs — A highly efficient and novel catalytic system for aerobic oxidation of alcohols to carbonyls and synthesis of DFF from HMF

Paper ID Volume ID Publish Year Pages File Format Full-Text
49313 46736 2016 4 PDF Available
Title
Bi (NO3)3·5H2O and cellulose mediated Cu-NPs — A highly efficient and novel catalytic system for aerobic oxidation of alcohols to carbonyls and synthesis of DFF from HMF
Abstract

•Bi (NO3)3·5H2O and Cu-NPs@Cellulose as a versatile catalyst for oxidation of alcohols•Oxidation of 5-hydroxymethyl furfural to 2,5-diformylfuran (82% yield)•Oxidation of secondary aromatic alcohol to ketones with 100% conversion•Very high efficiency, broader functional group tolerance & short reaction time•Primary aromatic alcohols to aldehydes (60–80% conv.)

A highly efficient and versatile catalytic system for oxidation of primary and secondary aromatic alcohols to carbonyls has been developed. High efficiency, general synthetic applicability, broader functional group tolerance and versatility towards oxidation of both primary and secondary aromatic alcohols are the key features of this green and sustainable protocol. Selective oxidation of 5-hydroxymethyl furfural (HMF) to biofuel 2,5-diformylfuran (DFF) has been observed in excellent yields. Use of sustainable bio-polymer cellulose as a Cu-nanoparticle support makes the catalytic system environmentally benign.

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Keywords
Cellulose; Cu-nanoparticles; Bismuth nitrate; Oxidation; Alcohols; HMF; Sustainable
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Bi (NO3)3·5H2O and cellulose mediated Cu-NPs — A highly efficient and novel catalytic system for aerobic oxidation of alcohols to carbonyls and synthesis of DFF from HMF
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 77, 5 March 2016, Pages 9–12
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us