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An easily recoverable and recyclable homogeneous polyester-based Pd catalytic system for the hydrogenation of α,β-unsaturated carbonyl compounds

Paper ID Volume ID Publish Year Pages File Format Full-Text
49386 46740 2015 6 PDF Available
Title
An easily recoverable and recyclable homogeneous polyester-based Pd catalytic system for the hydrogenation of α,β-unsaturated carbonyl compounds
Abstract

•trans-[Pd(OAc)2(L)2] was synthesized from Pd(OAc)2 and the poly(l-lactide) (L).•trans-[Pd(OAc)2(L)2] was used as catalytic precursor in hydrogenations.•trans-[Pd(OAc)2(L)2] is a homogeneous catalytic precursor.•The homogeneous catalyst can be easily recovered from the reaction mixture.•The catalytic system maintained its activity in recycle experiments.

Homogeneous catalysis is an efficient tool to carry out hydrogenation processes but the major drawback is represented by the separation of the expensive catalyst from the product mixture. In this view we prepared a polyester-based Pd catalytic system that offers the advantages of both homogenous and heterogeneous catalyses: efficacy, selectivity and recyclability. Here its application in the hydrogenation of selected α,β-unsaturated carbonyl compounds is described.

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Keywords
Hydrogenation; Homogeneous catalysis; Palladium; Macrocomplexes; Polyester
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An easily recoverable and recyclable homogeneous polyester-based Pd catalytic system for the hydrogenation of α,β-unsaturated carbonyl compounds
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 69, 5 September 2015, Pages 228–233
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us