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An effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate

Paper ID Volume ID Publish Year Pages File Format Full-Text
49398 46741 2016 4 PDF Available
Title
An effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate
Abstract

•An effective Ni2P/TiO2 catalyst was proposed for dimethyl oxalate hydrogenation.•A 93.0% conversion of dimethyl oxalate was obtained under 210 °C.•A selectivity of 88.0% to methyl glycolate was achieved under 210 °C.•Ni2P/TiO2 catalyst showed a superior stability which can be performed for 3600 h.

An effective and stable bifunctional Ni2P/TiO2 catalyst was proposed for gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. A 93.0% conversion of DMO with a selectivity of 88.0% to methyl glycolate was observed under 210 °C. Moreover, the catalyst showed an excellent stability which can be performed for 3600 h under the reaction conditions of 230 °C, 3 MPa H2 and the weight space velocity of 0.1 h− 1.

Graphical abstractAn effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate with an excellent stability (3600 h) was proposed.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Dimethyl oxalate; Methyl glycolate; Hydrogenation; Ni2P
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An effective and stable Ni2P/TiO2 catalyst for the hydrogenation of dimethyl oxalate to methyl glycolate
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 73, 5 January 2016, Pages 46–49
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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