fulltext.study @t Gmail

Influence of crystal size of HZSM-5 on hydrodeoxygenation of eugenol in aqueous phase

Paper ID Volume ID Publish Year Pages File Format Full-Text
49442 46745 2014 5 PDF Available
Title
Influence of crystal size of HZSM-5 on hydrodeoxygenation of eugenol in aqueous phase
Abstract

•ZSM-5 of smaller crystal size shows better HDO activity.•Diffusional limitation restricts the catalytic activity of micro-ZSM-5.•The activities of nano- and submicro- ZSM-5 are proportional to the acid sites.

Hydrodeoxygenation of eugenol to hydrocarbons in aqueous phase can be catalyzed by the combination of Pd/C and HZSM-5. In this paper, micro-, submicro- and nano-sized HZSM-5 samples were chosen as catalysts to investigate the influence of crystal size of HZSM-5 on the hydrolysis and dehydration. It was found that the formation rates of hydrocarbons were correlated with the total acidic sites of the submicro- and nano-sized HZSM-5 samples; while for the micro-sized sample, a much lower hydrocarbon formation rate was observed. Meanwhile, HZSM-5 with larger crystal size showed a lower hydrocarbon formation rate even with higher acid density.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
RRAFCDWBNXTKKO-UHFFFAOYSA-N; PXIKRTCSSLJURC-UHFFFAOYSA-N; FLNSLKJOWVMPEE-UHFFFAOYSA-N; YVPZFPKENDZQEJ-UHFFFAOYSA-NHydrodeoxygenation; Eugenol; Crystal size; ZSM-5
First Page Preview
Influence of crystal size of HZSM-5 on hydrodeoxygenation of eugenol in aqueous phase
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 56, 5 November 2014, Pages 123–127
Authors
, , , , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us