fulltext.study @t Gmail

New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol

Paper ID Volume ID Publish Year Pages File Format Full-Text
49543 46751 2015 4 PDF Available
Title
New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol
Abstract

•Bulk Ni3P catalysts are synthesized by a hydrothermal method for the first time.•The synthesized Ni3P catalysts present morphology of hexagonal prisms.•The synthesized Ni3P catalysts are tested for glycerol hydrogenolysis to propanediol.•The synthesized Ni3P catalysts exhibit a low-temperature activity for hydrogenolysis.

Transitional metal phosphides were found to have outstanding activity and stability in catalytic hydrotreatments. The bulk trinickel phosphide catalyst with the smallest phosphorus content among the nickel phosphides were synthesized by a hydrothermal method followed by an annealing treatment, and the resulting bulk trinickel phosphide catalysts presented a high purity and morphology of hexagonal prisms. The optimized synthesis conditions include a P:Ni ratio of 3 to 1 and a pH value of 5 in the hydrothermal synthesis stage and a calcination temperature of 773 K in the annealing treatment. The synthesized trinickel phosphides exhibited a low-temperature activity to selective glycerol hydrogenolysis and the high selectivity to 1,2-propanediol.

Keywords
PEDCQBHIVMGVHV-UHFFFAOYSA-NTrinickel phosphide; Hydrothermal synthesis; Glycerol; Hydrogenolysis; 1,2-Propanediol
First Page Preview
New bulk nickel phosphide catalysts for glycerol hydrogenolysis to 1,2-propanediol
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 59, 10 January 2015, Pages 180–183
Authors
, , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us