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A novel high-stability Au(III)/Schiff-based catalyst for acetylene hydrochlorination reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
49581 46755 2014 5 PDF Available
Title
A novel high-stability Au(III)/Schiff-based catalyst for acetylene hydrochlorination reaction
Abstract

•[AuCl2(phen)]Cl catalyst is synthesized and applied in acetylene hydrochlorination.•[AuCl2(phen)]Cl catalyst displays excellent stability for acetylene hydrochlorination.•N-containing ligands inhibit the reduction of active Au3 + component.

Herein, we reported on the application of an Au(III)/Schiff-based catalyst in acetylene hydrochlorination reaction. The [AuCl2(phen)]Cl catalyst exhibited excellent stability, and acetylene conversion was maintained at > 90% after 40 h of operation. The excellent stability of the [AuCl2(phen)]Cl catalyst was attributed to the presence of the 1,10-phenanthroline ligand that partially inhibited the reduction of the Au3 + active component.

Keywords
[AuCl2(phen)]Cl; Acetylene hydrochlorination
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A novel high-stability Au(III)/Schiff-based catalyst for acetylene hydrochlorination reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 54, 5 September 2014, Pages 61–65
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
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