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Efficient aerobic oxidation of alcohols using magnetically recoverable catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
49587 46755 2014 3 PDF Available
Title
Efficient aerobic oxidation of alcohols using magnetically recoverable catalysts
Abstract

•A simple, highly efficient and green protocol for the oxidation of benzoin•Fe(II) and Fe(III) are necessary for oxidation.•Magnetite not only acts as a heterogeneous catalyst, but also as an oxidant.•Nitro alcohols were converted into nitro ketones successfully in the presence of air.

A simple, highly efficient and mild catalytic aerobic oxidation of alcohol, in particularly benzoin was studied using iron oxide nanoparticles as a reusable catalyst. Moreover, benzyl was synthesized in large scale using inexpensive, readily available and environmentally friendly protocol in the presence of air. This novel and green methodology will allow further development not only in the geochemistry, but also in the oxidation of alcohols to replace expensive metals and corrosive reagents.

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Keywords
Benzoin; Heterogeneous; Magnetite; Nitro alcohols; Oxidation
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Efficient aerobic oxidation of alcohols using magnetically recoverable catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 54, 5 September 2014, Pages 91–93
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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