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Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates

Paper ID Volume ID Publish Year Pages File Format Full-Text
49671 46759 2014 5 PDF Available
Title
Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates
Abstract

•Azaphosphatranes in the synthesis of styrene carbonate from CO2 and epoxides•Substitution tuning at the PH+ site led to increased activity and robustness.•H-bonding between F or OMe groups and PH+ results in larger stabilizing effects.

Various N-substituted azaphosphatranes have been prepared and successfully applied to the synthesis of styrene carbonates from CO2 and epoxides. Enhancement of the catalytic properties of the azaphosphatrane was achieved upon pre-organization of the active site through hydrogen-bonding.

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Keywords
Azaphosphatranes; Cyclic carbonates; CO2 chemical valorization; Homogeneous catalysis; Epoxides
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Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 52, 5 July 2014, Pages 26–30
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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