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Synthesis of a porphyrinic polymer for highly efficient oxidation of arylalkanes in water

Paper ID Volume ID Publish Year Pages File Format Full-Text
49725 46763 2015 5 PDF Available
Title
Synthesis of a porphyrinic polymer for highly efficient oxidation of arylalkanes in water
Abstract

•Porphyrin moieties were immobilized into rigid, stable and porous CPF-1.•CPF-1 was simply metalated to result in a highly active catalyst Mn-CPF-1.•Mn-CPF-1 exhibits high activity and selectivity in heterogeneous catalysis.•Mn-CPF-1 is much superior to the homogeneous counterpart.

A highly stable covalent-porphyrinic framework Mn-CPF-1 was synthesized by reaction of cyanuric chloride and tetraphenylamine porphyrin (TAPP) and subsequent metallation. Mn-CPF-1 exhibits remarkable catalytic activity and stability on catalytic oxidation of arylalkanes in water under mild conditions, which is much superior to the homogeneous analog Mn-tetraphenylporphyrin (Mn-TPP) under identical conditions.

Graphical abstractA highly stable and porous porphyrinic material CPF-1 has been successfully designed and constructed, which can be easily metalated with manganese ions to realize high catalytic efficiency and stability on oxidation of arylalkanes in water at room temperature.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Biomimetic; Heterogeneous catalysis; Metal-organic framework; Metalloporphyrin; Porous organic polymer
First Page Preview
Synthesis of a porphyrinic polymer for highly efficient oxidation of arylalkanes in water
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 66, 5 June 2015, Pages 116–120
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis