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Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complex with sodium hypochlorite as oxidant

Paper ID Volume ID Publish Year Pages File Format Full-Text
49752 46764 2014 4 PDF Available
Title
Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complex with sodium hypochlorite as oxidant
Abstract

•Chiral Mn(III)-salen complex catalyzed OKR of secondary alcohols.•Sodium hypochlorite replaced PhI(OAc)2 as an oxidant for the reaction.•Sodium hypochlorite is very cheap and easily available.•The novel protocol is very efficient for the OKR of a variety of secondary alcohols.

Chiral Mn(III)-salen complex catalyzed oxidative kinetic resolution (OKR) of secondary alcohols has been achieved with cheap and easily available sodium hypochlorite (NaClO) as oxidant. The novel protocol is very efficient for the OKR of a variety of secondary alcohols at room temperature.

Graphical abstractChiral Mn(III)-salen complex catalyzed oxidative kinetic resolution (OKR) of secondary alcohols has been achieved with sodium hypochlorite as oxidant in the presence of catalytic amount of bromine. This novel protocol is very efficient for the OKR of a variety of secondary alcohols.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Enantioselective oxidation; Chiral Mn(III)-salen complex; Sodium hypochlorite; Secondary alcohols
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Enantioselective oxidation of racemic secondary alcohols catalyzed by chiral Mn(III)-salen complex with sodium hypochlorite as oxidant
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 45, 5 February 2014, Pages 114–117
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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