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A robust chemo-enzymatic lactone synthesis using acyltransferase from Mycobacterium smegmatis

Paper ID Volume ID Publish Year Pages File Format Full-Text
49771 46765 2016 4 PDF Available
Title
A robust chemo-enzymatic lactone synthesis using acyltransferase from Mycobacterium smegmatis
Abstract

•A robust Baeyer-Villiger chemo-enzymatic method for lactone synthesis is described•The new application of acyltransferase isolated from Mycobacterium smegmatis is proposed•Acyltransferase exhibited high activity and stability under harsh reaction conditions

The new application of acyltransferase, isolated from Mycobacterium smegmatis for the chemo-enzymatic Baeyer-Villiger oxidation of cyclic ketones to lactones was demonstrated. Acyltransferase exhibited high activity, and high stability under harsh reaction conditions, like oxidation with 60% aq. H2O2 at 45 °C. This paves the way to a novel robust chemo-enzymatic method for lactone synthesis with high yields.

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Keywords
Acyltransferase; Baeyer-Villiger oxidation; Lactones; Hydrogen peroxide
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A robust chemo-enzymatic lactone synthesis using acyltransferase from Mycobacterium smegmatis
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 81, 5 June 2016, Pages 37–40
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
Online Support
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