fulltext.study @t Gmail

Hydrogen generation at ambient conditions: AgPd bimetal supported on metal–organic framework derived porous carbon as an efficient synergistic catalyst

Paper ID Volume ID Publish Year Pages File Format Full-Text
49809 46768 2016 5 PDF Available
Title
Hydrogen generation at ambient conditions: AgPd bimetal supported on metal–organic framework derived porous carbon as an efficient synergistic catalyst
Abstract

•Ag–Pd bimetal supported on the MOF-5 derived nanoporous carbon was fabricated.•The catalyst exhibited excellent catalytic activity for the dehydrogenation of FA.•The initial turnover frequency was 854 h− 1.

An efficient synergistic catalyst, AgPd bimetal supported on metal–organic framework derived porous carbon (AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H2 selectivity and high catalytic activity in hydrogen generation from formic acid at ambient conditions. The initial turnover frequency could reach as high as 854 h− 1. The combination of distinct interaction among bimetal, support and high dispersion of nanoparticles drastically enhances the catalytic performance of the resulted catalyst.

Graphical abstractAn efficient synergistic catalyst, AgPd bimetal supported on metal–organic framework derived porous carbon (AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H2 selectivity and high catalytic activity in hydrogen generation from formic acid. At ambient conditions, the initial turnover frequency could reach as high as 854 h− 1.Figure optionsDownload full-size imageDownload as PowerPoint slide

Keywords
Metal–organic framework derived porous carbon; AgPd bimetal; Formic acid; Dehydrogenation
First Page Preview
Hydrogen generation at ambient conditions: AgPd bimetal supported on metal–organic framework derived porous carbon as an efficient synergistic catalyst
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 78, 10 March 2016, Pages 17–21
Authors
, , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us