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Cyclopentadienyliron dicarbonyl dimer: A simple tool for the hydrosilylation of aldehydes and ketones under air

Paper ID Volume ID Publish Year Pages File Format Full-Text
49816 46768 2016 3 PDF Available
Title
Cyclopentadienyliron dicarbonyl dimer: A simple tool for the hydrosilylation of aldehydes and ketones under air
Abstract

•[CpFe(CO)2]2 promotes hydrosilylation of various aldehydes and ketones.•The procedure is air-tolerant and an organic solvent is unnecessary.•This catalytic system allows a minimal economic and environmental impact.

The readily available iron complex [CpFe(CO)2]2 (1) exhibits good catalytic activity in the hydrosilylation of aldehydes and ketones in the presence of diethoxymethylsilane. The procedure described is air-tolerant and applicable to a wide range of substrates.

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Keywords
Aldehydes; Hydrosilylation; Iron; Ketones; Reduction
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Cyclopentadienyliron dicarbonyl dimer: A simple tool for the hydrosilylation of aldehydes and ketones under air
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 78, 10 March 2016, Pages 52–54
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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