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Controlled deposition of Pd and In on carbon fibers by sequential electroless plating for the catalytic reduction of nitrate in water

Paper ID Volume ID Publish Year Pages File Format Full-Text
49818 46768 2016 5 PDF Available
Title
Controlled deposition of Pd and In on carbon fibers by sequential electroless plating for the catalytic reduction of nitrate in water
Abstract

•In particles were deposited on the top of tiny Pd films formed on carbon fibers.•The structure of the films changed after catalytic nitrate reduction.•PdIn/carbon fibers having a Pd:In ratio of 2 was the most active catalyst.•High activity and selectivity were obtained using a structured support.

Catalysts containing 1.8 wt.% of Pd and different In loadings were prepared by sequential electroless plating on activated carbon felts (ACF). Homogeneous structures were obtained, with In particles deposited at the top of a tiny Pd film. The catalyst with the higher In loading (Pd:In ratio of 2.0) presented high activity and good selectivity towards nitrogen, with negligible deactivation after 6 h of time-on-stream and three consecutive nitrate pulses. Besides the promising catalytic behavior, PdIn/ACF have the advantages of an open structure, which is highly accessible to the reactants, with no need of separation after the reaction.

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Keywords
PdIn/activated carbon felts; Electroless plating; Nitrate reduction; Water purification
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Controlled deposition of Pd and In on carbon fibers by sequential electroless plating for the catalytic reduction of nitrate in water
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 78, 10 March 2016, Pages 59–63
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Price was $35.95
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Price after discount Only $4.95
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Full-text PDF Download
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