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3D-network porous polymer based on calix[4]resorcinarenes as an efficient phase transfer catalyst in regioselective conversion of epoxides to azidohydrins

Paper ID Volume ID Publish Year Pages File Format Full-Text
49824 46769 2012 5 PDF Available
Title
3D-network porous polymer based on calix[4]resorcinarenes as an efficient phase transfer catalyst in regioselective conversion of epoxides to azidohydrins
Abstract

The present study, for the first time, describes the application of 3D‐network polymer based on calix[4]resorcinarene, as an efficient heterogeneous and phase transfer catalyst for regioselective azidolysis of epoxides. The surface morphology and the structure of this polymer were investigated by atomic force microscopy (AFM). This method offers several advantages including clean reactions, ease of work-up and reusability of the catalyst.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The catalyst shows porosity contains both hydrophilic and hydrophobic layers. ► The catalyst can be recovered and recycled. ► The water tolerant catalysts can be introduce as inexpensive and nonpolluting reagent. ► The catalyst is resistant and active for the reaction. ► The desired products were performed in an environmental area.

Keywords
Calix[4]resorcinarenes; Network polymer; Azidohydrins; AFM
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3D-network porous polymer based on calix[4]resorcinarenes as an efficient phase transfer catalyst in regioselective conversion of epoxides to azidohydrins
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 29, 5 December 2012, Pages 1–5
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us