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Solid acid-catalyzed conversion of furfuryl alcohol to alkyl tetrahydrofurfuryl ether

Paper ID Volume ID Publish Year Pages File Format Full-Text
49906 46773 2015 4 PDF Available
Title
Solid acid-catalyzed conversion of furfuryl alcohol to alkyl tetrahydrofurfuryl ether
Abstract

•HZSM-5 catalyzes furfuryl alcohol etherification with methanol and ethanol.•Raney Ni hydrogenates alkyl furfuryl ether into alkyl tetrahydrofurfuryl ether.•Alkyl tetrahydrofurfuryl ether improves the cetane number.

The acidic zeolite HZSM-5 (Si/Al = 25) achieved 58.9% selectivity of methyl furfuryl ether (MFE) and 44.8% selectivity of ethyl furfuryl ether (EFE) from etherification of furfuryl alcohol with methanol and ethanol. MFE and EFE were quantitatively hydrogenated into methyl tetrahydrofurfuryl ether (MTE) and ethyl tetrahydrofurfuryl ether (ETE) using a Raney Ni catalyst.

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Keywords
XPFVYQJUAUNWIW-UHFFFAOYSA-NMethyl tetrahydrofurfuryl ether; Ethyl tetrahydrofurfuryl ether; Furfuryl alcohol; Solid acid; Diesel additive
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Solid acid-catalyzed conversion of furfuryl alcohol to alkyl tetrahydrofurfuryl ether
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 58, 5 January 2015, Pages 76–79
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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